代表性科研项目 1.新型含羰基富勒烯衍生物的合成及性能研究(国家自然科学基金),主持 2.新型苯并三唑类紫外线吸收剂的合成与工艺优化(吉林省教育厅),主持 3.有机电化学方法区域选择性合成富勒烯多加成衍生物(国家自然科学基金),参与 4.C76衍生物的制备及对其反应选择性和机理的探讨(国家自然科学基金),参与 代表性成果 [1] Li, Wenzhong, Ran Shi, Sen Chen, Xuesi Zhang, Wei Peng,Si Chen, Jiazhu Li, Xin-Ming Xu, Yan-Ping Zhu, and Xueyuan Wang, Synthesis of diverse pentasubstituted pyrroles by a Gold (I)-catalyzed cascade rearrangement-cyclization of tertiary enamide.J. Org. Chem.2022,87(5), 3014-3024. [2]Li, Wenzhong, Baibai Wan, Ran Shi,Si Chen, Jiazhu Li, Fangzhen Wang, Hexu Niu, Xin-Ming Xu, and Wei-Li Wang, Catalyst-free one-pot cascade cyclization: An efficient synthesis of isoindolobenzoxazinones and isoindoloquinazolinones derivatives.Tetrahedron, 2022,104, 132571. [3]Li, Wenzhong, Yu Wang, Huijing Qi, Ran Shi, Jiazhu Li,Si Chen, Xin-Ming Xu, and Wei-Li Wang, Diverse privileged N-polycyclic skeletons accessed from a metal-free cascade cyclization reaction.Org. Biomol. Chem.2021,19 (37), 8086-8095. [4]Si Chen,Wei-WeiYang,Hui-LeiHou,Zong-JunLiandXiangGao,Reactions of [60]Fullerene with Acetone under Basic Condition: Nucleophilic Ring Opening of the [5,6]-Cyclopropane in C60and Formation of the Substituted Methano[60]Fulleroids.J. Org. Chem.2021,86(6),4843-4848. [5]Han-Lin Yang,Li-JunXu,Wen-Zhong Li, TaoSun, Bao-RongDuan,Si ChenandXiang Gao,Base-iodine-promoted metal-catalyst-free reactions of [60]fullerene with β-keto esters for the selective formation of [60]fullerene derivatives.RSC Adv.2020,10(41),24549-24554. [6]Si Chen,Zong-Jun Li,and Xiang Gao,Base-Promoted Oxidative Cycloaddition Reaction of [60]Fullerene with Ethyl Acetoacetate for C60Bis-2’,3’-Dihydrofuran Derivatives: Effect of Bulky Addends.J. Org. Chem.2016,81(1),121−128. [7]Si Chen,Zong-Jun Li, Shui-Hui Li and Xiang Gao,Base-Promoted Consecutive Enolate Addition Reaction of [60]Fullerene with Ketones.Org.Lett.2015,17(21),5192−5195. [8]Hui-LeiHou,Zong-Jun Li, Shu-Hui Li,Si Chenand Xiang Gao, Hydroxy-InitiatedConversion of Aromatic Nitriles to Imidazolines:Fullerenesvs TCNE.Org.Lett.2013,15(18),4646-4649. [9]陈鸶,高翔,杨斌,杨翰林.碘-碱体系中选择性制备不同环状富勒烯衍生物的方法(发明专利,专利号:ZL201910302627.5)(已授权) |