科研项目： 1. 过渡金属催化醚氧原子α位C(sp3)–F键形成反应研究，国家自然科学基金项目(U1504210), 2016.1-2018.12，主持 2. 钌催化导向基协助的芳烃远程硒化反应研究，国家自然科学基金项目(21801007), 2019.01-2021.12，主持 3. 喹啉衍生物区域选择性三氟甲基化反应研究，河南省教育厅高校科技创新团队(18IRTSTHN004), 2018.1-2019.12，主持 4.可见光催化体系发展醚氧原子α-位 C–S键构建反应研究，中国博士后科学基金57批面上项目(2015M572110)，2015.1-2016.12，主持 5. 新型含三氟甲基喹啉药物分子的合成研究，河南省科技攻关项目(172102310172)，2016.1-2017.12，主持 代表性论文： 1. Palladium-Catalyzed C–H Aminations of Anilides withN-Fluorosulfonimide Kai Sun, Yan Li, Tao Xiong, Jingping Zhang, Qian Zhang* J. Am. Chem. Soc.,2011,133, 1694. (ESI高被引论文) 2. Efficient Imidation of C(sp3)–H Bonds adjacent to Oxygen Atoms of Aryl Ethers under Metal-free Conditions Kai Sun,*Xin Wang, Gang Li, Zhonghong Zhu, Yongqing Jiang, Beibei Xiao Chem. Commun., 2014,50, 12880. 3. Copper-Catalyzed Cross-Dehydrogenative C−N Bond Formation of Azines with Azoles: Overcoming the Limitation of Oxidizing N−O Activation Strategy Kai Sun,*Xin Wang, Lulu Liu, Jingjing Sun, Zhiguo Zhang, Guisheng Zhang* ACS Catal., 2015,5, 7194. 4. Regioselective, Molecular Iodine-Mediated C3 Iodination of Quinolines Kai Sun,*Yunhe Lv, Junjie Wang, Jingjing Sun, Lulu Liu, Xin Wang* Org. Lett., 2015,17, 4408. 5. Copper-Catalyzed Arenes Amination with Saccharins Kai Sun, Yan Li,* Qian Zhang* Sci. China Chem.,2015,58, 1354. 6.Peroxodisulfate-Mediated Selenoamination of Alkenes yielding Amidoselenide- Ccontaining Sulfamides and Azoles Kai Sun,* Xin Wang, Yunhe Lv, Gang Li, Hezhen Jiao, Yangyang Li, Chong Zhang, Lin Liu* Chem. Commun., 2016,52,8471. 7. Metal-free Selenosulfonylation of Alkynes: Rapid Access toβ-(Seleno)vinyl Sulfones via a Cationic-species-induced Pathway Kai Sun,Xin Wang, Fangfang Fu, Chong Zhang, Yao Chen, Lin Liu* Green Chem., 2017, 19, 1490. 8. Direct Access to β-Selenosulfones at Room Temperature through Selenosulfonylation of Alkene Kai Sun*,Yunhe Lv, Zuodong Shi, Fangfang Fu, Chong Zhang, Zhiguo Zhang* Sci. China Chem.,2017,60, 730. 9. Metal-free Tetra-n-butylammonium Bromide-mediated Aerobic Oxidative Synthesis of β-Ketosulfones from Styrenes Xin Wan,Kai Sun*and Guisheng Zhang* Sci. China Chem.,2017, 60, 353. 10. Aptasensors for the Selective Detection of Alpha-synuclein Oligomer by Colorimetry, Surface Plasmon Resonance and Electrochemical Impedance Spectroscopy Kai Sun,Ning Xia, Lijuan Zhao, Ke Liu, Wenjing Hou, Lin Liu* Senor Actuat B-Chem.,2017,245, 87. 11. Synthesis of (E)-β-Selenovinyl Sulfones through a Multicomponent Regio- and Stereospecific Selenosulfonation of Alkynes with Insertion of Sulfur Dioxide Kai Sun,*Zuodong Shi, Zhenhua Liu, Baixue Luan, Jiali Zhu, Yanru Xue Org. Lett., 2018,20, 6687. (ESI高被引论文) 12.Copper-Catalyzed Radical Selenodifluoromethylation of Alkenes: Access to CF2-Containing γ-Lactams Kai Sun,*Songnan Wang, Ranran Feng, Yixiao Zhang, Xin Wang, Zhiguo Zhang,* Bing Zhang Org. Lett., 2019,21, 2052. (ESI高被引论文) 13. C–H Imidation and Dual C–H Bond Aminobromination of Five-Membered Heterocycles Kai Sun*,Yali Li, Ranran Feng, Shiqiang Mu, Xin Wang, Bing Zhang J. Org. Chem.,2020,85,1001.( ESI高被引论文) 14. Electrochemically Enabled Intramolecular and Intermolecular Annulations of Alkynes Kai Sun, *Jia Lei, Yingjie Liu, Bing Liu, Ning Chen Adv. Synth. Catal.,2020,362, 3709. (VIP Publishing) 15. Oxidative Radical Relay Functionalization for the Synthesis of Benzimidazo[2,1-a]iso-quinolin- 6(5H)-ones Kai Sun, *Guofeng Li, Yuyang Li, Jie Yu, Qing Zhao, Zhiguo Zhang,* Guisheng Zhang* Adv. Synth. Catal.,2020,362, 1947. 16. An Organoselenium-Catalyzed N1- and N2-SelectiveAza-Wacker Reaction of Alkenes with Benzotriazoles Xin Wang, Qinlin Wang, Yanru Xue,Kai Sun,* Lanlan Wu, Bing Zhang * Chem. Commun., 2020,56, 4436. 17. Recent Advances in Tandem Selenocyclization and Tellurocyclization with Alkenes and Alkynes Kai Sun,*Xin Wang, Chao Li, He Wang, Lei Li* Org. Chem. Front.,2020,7, 3100 (邀稿综述). 18. Fluorination and Fluoroalkylation of Alkenes/Alkynes to Construct Fluoro-Containing Heterocycle Xin Wang, Jia Lei, Yingjie Liu, Yong Ye, Jiazhu Li,Kai Sun* Org. Chem. Front.,2021,8, 2079 (综述). 19. Metal-Free Organoselenium-Enabled Radical Relay Azidation–Carbocyclization Xin Wang, Sa Guo, Yan Zhang, Zhiguo Zhang,* Guisheng Zhang,* Yong Ye,Kai Sun* Adv. Synth. Catal.,2021,363, 3290-3296. 20. Recent Advances in the Synthetic Use of Migration Reactions of Allyl Alcohols Yun Xing, Chen Li, Jianping Meng, Zhen Zhang, Xin Wang*, Zhichuan Wang, Yong Ye,Kai Sun* Adv. Synth. Catal., 2021,363, 3913-3936. 21. Update on the Synthesis of N-Heterocycles via Cyclization of Hydrazones (2017–2021) Yunhe Lv, Jianping Meng, Chen Li, Xin Wang*, Yong Ye,Kai Sun* Adv. Synth. Catal., 2021,363, 5235-5265. 22. Radical Selenation of C(sp3)–H Bonds to Asymmetric Selenides and Mechanistic Study Xin Wang, Jia Lei, Sa Guo, Yan Zhang, Yong Ye, Shi Tang,Kai Sun* Chem. Commun., 2022,58, 1526-1529. 著作： 《有机化学基本原理及应用实践研究》 2016年，中国原子能出版社，主编，ISBN ：978-7-5022-7330-9. 获奖情况： 唐敖庆化学奖学金 2012年 国家研究生奖学金 2013年 河南省第三届自然科学学术论文一等奖 2015年 河南省第十三届“挑战杯”大学生科技作品竞赛“优秀指导教师” 2017年 河南省青年骨干教师 2019年 河南省教育厅科技成果一等奖 2020年 |
